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Type: 
Journal
Description: 
We present a comprehensive study on the formation of micrometer-sized, textured hexagonal diamond silicon (hd-Si) crystals via nanoindentation followed by annealing. Utilizing advanced characterization techniques such as polarized Raman spectroscopy, high-resolution transmission electron microscopy, and electron energy-loss spectroscopy, we demonstrate the successful transformation of silicon into high-quality hd-Si. The experimental results are further supported by first-principles calculations and molecular dynamics simulations. Notably, the hd-Si phase consists of nanometer-sized grains with slight misorientations, organized into large micrometer-scale textured domains. These findings underscore the potential of nanoindentation as a precise and versatile tool for inducing pressure-driven phase transformations, particularly for the stabilization of hexagonal silicon. The textured nature of hd-Si also presents a unique opportunity to tailor its optical properties, opening new avenues for its application in semiconductor and optoelectronic devices.
Publisher: 
Publication date: 
10 Oct 2024
Authors: 

Mouad Bikerouin, Anna Marzegalli, Davide Spirito, Gerald JK Schaffar, Corrado Bongiorno, Fabrizio Rovaris, Mohamed Zaghloul, Agnieszka Anna Corley-Wiciak, Antonio M Mio, Leo Miglio, Verena Maier-Kiener, Giovanni Capellini, Emilio Scalise

Biblio References: 
Origin: 
arXiv preprint arXiv:2410.08372