In this work we present the response of a new large volume 4H Silicon Carbide (SiC) detector to 14 MeV neutrons. The device has an active thickness of 100 μ m (obtained by epitaxial growing) and an active area of 25 mm 2. Tests were conducted at the ENEA-Frascati Neutron Generator facility by using 14.1 MeV neutrons. The SiC detector performance was compared to that of Single-Crystal Diamond (SCD) detectors. The SiC response function was successfully measured and revealed a very complex structure due to the presence in the detector of both Silicon and Carbon atoms. Nevertheless, the flexibility in the SiC manufacturing and the new achievements in terms of relatively large areas (up 1x1 cm 2) and a wide range of thicknesses makes them an interesting alternative to diamond detectors in environments where limited space and high neutron fluxes are an issue, ie modern neutron cameras or in-vessel …